133284-78-3Relevant articles and documents
Diastereoselective Formation of Tricarbonyliron(0) Complexes of 1-Aza-1,3-dienes Bearing Chiral Substituents
Morris, K. Gail,Thomas, Susan E.
, p. 97 - 101 (2007/10/02)
Syntheses of two series of novel 1-aza-1,3-dienes bearing chiral substituents on nitrogen i and But) and PhCH=CHCH=NCH(R)Me (R=Et Pri and But)> are described and the stereochemical outcome of their complexation reactions with Fe2(CO)9 reported.Diastereomeric ratios of 93:7 and 94:6 are observed on complexation of PhCH=CHCH=NCH(But)Ph 10 and PhCH=CHCH=NCH(But)Me 19 respectively.The structures of the major diastereomers 10 and 19 have been determined by NOE measurements.