1333245-13-8

Basic information

• Product Name: 1,3,5-triethyl-2,4,6-tris[3-{3-(4-pyridyl)ureido}-phenoxymethyl]benzene
• CAS NO: 1333245-13-8
• Molecular Weight: 886.023
• Mol File: 1333245-13-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,3,5-triethyl-2,4,6-tris[3-{3-(4-pyridyl)ureido}-phenoxymethyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5-triethyl-2,4,6-tris[3-{3-(4-pyridyl)ureido}-phenoxymethyl]benzene(1333245-13-8)
• EPA Substance Registry System: 1,3,5-triethyl-2,4,6-tris[3-{3-(4-pyridyl)ureido}-phenoxymethyl]benzene(1333245-13-8)

Safety Data

• Hazardous Substances Data: 1333245-13-8(Hazardous Substances Data)

Upstream product

• 1002360-41-9 1,3,5-tris(3-aminophenoxymethyl)-2,4,6-triethylbenzene 
• 70067-45-7 4-pyridyl isocyanate 

Relevant articles and documents

Construction of two- or three-component low molecular weight gel systems

Pyridyl group-bound tris-urea 2, whose structure issimilar to the tris-urea low molecular weight gelator (LMWG) 1, was synthesized. Addition of a trace amount of 2 and Pd(OAc)2 to 1 resulted in a reduction in the critical gelation concentration (CGC) in acetone. Metal-ligand interaction between Pd(OAc)2 and the pyridyl group of 2 assist the gelation. Assistance by intermolecular hydrogen bonding was also effective for gelation of acetone. An acetone gel of 1 was formed at half the value of the CGC of 1 alone by adding a trace amount of 2 and isophthalicacid. Scanning electron microscopy (SEM) measurements of these aggregates showed structural alterations caused by the additive. A mixture of 1 and a trace amount of 2 in EtOAc gave a gel. Addition of 2 was essential to form the gel, because 1 alone did not gel EtOAc. SEM measurements indicated that 2 produced extension of the fibrous aggregates.