13335-50-7Relevant articles and documents
Generation of Hydrogen from Water: A Pd-Catalyzed Reduction of Water Using Diboron Reagent at Ambient Conditions
Ojha, Devi Prasan,Gadde, Karthik,Prabhu, Kandikere Ramaiah
, p. 5062 - 5065 (2016)
Production of hydrogen from renewable sources, particularly from water, is an intensive area of research, which has far-reaching relevance in hydrogen economy. A homogeneous catalytic method is presented for producing clean hydrogen gas from water, in a reaction of water with a diboron compound as the reductant, under ambient reaction conditions. The Pd-catalytic system is stable in water and displays excellent recyclability. Hydroxy analogues such as alcohols are compatible with the Pd/B2Pin2 system and generate hydrogen gas efficiently. The B2Pin2-H2O system, in the presence of palladium, is an excellent catalytic system for selective hydrogenation of olefins.
Development of a palladium on boron nitride catalyst and its application to the semihydrogenation of alkynes
Yabe, Yuki,Yamada, Tsuyoshi,Nagata, Saori,Sawama, Yoshinari,Monguchi, Yasunari,Sajiki, Hironao
supporting information; experimental part, p. 1264 - 1268 (2012/06/15)
The simple preparative method for a novel palladium supported on boron nitride catalyst (Pd/BN) was accomplished. Pd/BN is widely applicable for the semihydrogenation of mono- as well as disubstituted alkynes to furnish the corresponding alkenes in the presence of diethylenetriamine (DETA), which exhibits both an unprecedented acceleration effect toward the semihydrogenation and a suppression effect with regard to the overhydrogenation to alkanes. Copyright
Development of molecular sieves-supported palladium catalyst and chemoselective hydrogenation of unsaturated bonds in the presence of nitro groups
Maegawa, Tomohiro,Takahashi, Tohru,Yoshimura, Masatoshi,Suzuka, Hiroyasu,Monguchi, Yasunari,Sajiki, Hironao
supporting information; experimental part, p. 2091 - 2095 (2009/12/26)
The chemoselective hydrogenation of unsaturated bonds and azide functionalities is achieved in the presence of nitro groups by a heterogeneous palladium catalyst supported on molecular sieves (MS3A). The present method shows a widerange of applicability with regard to substrates and the catalyst can be easily prepared and reused at least three times without any loss of activity.