13340-46-0Relevant articles and documents
Platinum catalyzed hydrosilylation of alkynes: comparison of rates of addition of terminal olefins to internal alkynes
Lewis, Larry N.,Sy, Karen G.,Donahue, Paul E.
, p. 165 - 172 (1992)
The relative rates of platinum catalyzed hydrosilylation of terminal olefins versus internal alkynes were compared in competitive reactions. (EtO)3SiH added almost exclusively (97percent) to PhCCPh versus styrene.The reaction of (EtO)3SiH with equimolar amounts of 2-decyne and 1-hexene gave a 78:22 ratio of alkyne products 6/6' versus alkene product 7.The reaction of (EtO)3SiH with equimolar amounts of styrene and 1-phenyl-1-propyne gave a 78:22 ratio of alkyne products 10/10' to products 9.The silane, Me3SiOSiMe2H, reacted with equimolar amounts of 2-decyne and 1-hexene to give a 90:10 ratio of alkyne products 8/8' to alkene product 9.All of the products had E stereochemistry about the C=C double bond as determined by 29Si NMR (3J(Si-H)).
Efficient magnetically separable heterogeneous platinum catalyst bearing imidazolyl schiff base ligands for hydrosilylation
Huo, Yingpeng,Hu, Jiwen,Tu, Yuanyuan,Huang, Zhenzhu,Lin, Shudong,Luo, Xiaojiong,Feng, Chao
, (2021/02/06)
Reported herein is a magnetically separable heterogeneous nano catalyst Fe3O4@SiO2-biIMI- PtCl2, which is prepared by firstly applying a SiO2 coating onto readily synthesized magnetite nanoparticles via the hydrolysis condensation of tetraethyl orthosilicate (TEOS) under basic conditions, then modifying it using aminopropyl triethoxysilane and bis(imidazole) aldehyde, and finally incorporating a PtCl2 complex via coordination chemistry. The chemical structure and morphology of the nanocatalyst as well as the valence state and content of platinum within this catalyst were carefully characterized. This catalyst can mediate the hydrosilylation between 1-octene and hydrosilane, with the conversion of 1-octene reaching up to 99%, and it shows good regioselectivity as only β-adducts are identified. In addition, this catalyst can be reused for at least 5 cycles. The hydrosilylation reaction between different olefins and hydrosilanes can also be efficiently mediated by Fe3O4@SiO2-biIMI-PtCl2.
Platinum-Pyridine Schiff base complexes immobilized onto silica gel as efficient and low cost catalyst for hydrosilylation
Huo, Yingpeng,Hu, Jiwen,Liu, Feng,Wu, Jiapei,Zhang, Yikun,Zhang, Yalan,Wang, Qianyi
, p. 812 - 818 (2021/07/25)
A heterogeneous platinum catalyst with tridentate pyridine Schiff base ligands supported on silica gel is reported. The catalyst was fully characterized via FTIR, solid-state 13C NMR spectroscopy, X-ray photoelectron spectroscopy (XPS), N2 adsorption/desorption analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The catalyst showed potential application in mediating hydrosilylation reactions between olefins and hydrosilanes, and it can be reused for at least five cycles.
Platinum(II) complexes bearing bulky Schiff base ligands anchored onto mesoporous SBA-15 supports as efficient catalysts for hydrosilylation
Huo, Yingpeng,Hu, Jiwen,Lin, Shudong,Ju, Xingming,Wei, Yanlong,Huang, Zhenzhu,Hu, Yangfei,Tu, Yuanyuan
, (2019/04/26)
Reported herein is an easy-to-prepare novel heterogeneous catalyst of platinum complexes bearing binary ligands of bidentate naphthalenolimine and cyclo-1,5-octadiene that are anchored onto mesoporous silica SBA-15. The presence of the binary ligands not only stabilized the platinum, but also enabled the platinum atoms to form nanoclusters with diameters of ca 1?nm, and led to high platinum loading (8.69?wt%). Moreover, the platinum catalyst exhibited high catalytic activity towards hydrosilylation of terminal alkenes and styrene with silanes under mild and solvent-free conditions, with excellent regioselectivity.
