133401-36-2Relevant articles and documents
Formation of dimers that contain unbridged W(IV)/W(IV) double bonds
Lopez, Lourdes Pia H.,Schrock, Richard R.
, p. 9526 - 9527 (2004)
A tungsten neopentylidene complex has been found to decompose to yield a heterochiral dimer that contains a W=W double bond and no bridging ligands. Decompositions of related bisalkoxide complexes also yield compounds that contain an unsupported W=W double bond, while a sample of [Mo(NAr)(CH2-t-Bu)(OC6F5)]2 has been found to be a homochiral species related to [W(NAr)(CH2-t-Bu)(OC6F5)]2. Copyright
Synthesis and study of imidoalkyl complexes of tungsten(VI): Application of 14N NMR spectroscopy
Le Ny, Jean Pierre,Osborn, John A.
, p. 1546 - 1550 (2008/10/08)
Complexes of the type W(NR)(CH2But)3X have been synthetised by reaction of WOCl4 with RNCO, followed by alkylation with dineopentylmagnesium. The structures of these complexes and their adducts with Lewis acids