1335014-68-0

Basic information

• Product Name: imino(perfluorobutyl)(phenyl)-λ⁶-sulfanone
• Synonyms: imino(perfluorobutyl)(phenyl)-λ⁶-sulfanone
• CAS NO: 1335014-68-0
• Molecular Weight: 359.215
• Mol File: 1335014-68-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: imino(perfluorobutyl)(phenyl)-λ⁶-sulfanone(CAS DataBase Reference)
• NIST Chemistry Reference: imino(perfluorobutyl)(phenyl)-λ⁶-sulfanone(1335014-68-0)
• EPA Substance Registry System: imino(perfluorobutyl)(phenyl)-λ⁶-sulfanone(1335014-68-0)

Safety Data

• Hazardous Substances Data: 1335014-68-0(Hazardous Substances Data)

Upstream product

• 105279-34-3 phenyl nonafluorobutyl sulfide 
• 1111-78-0 ammonium carbamate 
• 1178899-18-7 N-acetyl-S-(nonafluorobutyl)-S-phenylsulfilimine 
• 1178899-44-9 ((perfluorobutyl)sulfinyl)benzene 

Downstream Products

• 1448157-79-6 O-(2,2,2-trichloroethyl) N-[(1,1,2,2,3,3,4,4,4-nonafluorobutyl)-oxo-phenyl-λ6-sulfanylidene]carbamoate 
• 1335015-69-4 N-[(1,1,2,2,3,3,4,4,4-nonafluorobutyl)-oxo-(phenyl)-λ6-sulfanylidene]benzamide 

Relevant articles and documents

One-Pot Synthesis of Aryl- and Alkyl S-Perfluoroalkylated NH-Sulfoximines from Sulfides

A general efficient one-pot synthesis of S-perfluoroalkylated NH-sulfoximines from sulfides has been developed using phenyliodine diacetate (PIDA) and ammonium carbamate. Remarkable rate enhancement with trifluoroethanol was observed, presumably due to H-bonding effects. These mild and metal-free conditions are compatible with -CH2F, -CFCl2, -CF2H, -CF2Br, -C4F9, and -CF3 groups, in both the alkyl- and aryl series. Based on a 19F NMR analysis, a λ6-acetoxysulfanenitrile intermediate was proposed.

Efficient copper-induced coupling between NH-fluoroalkylated sulfoximines and aryl iodides or bromides

A high yielding, simple, and flexible copper-based system for N-arylation of fluorinated sulfoximines is reported. Best results were achieved using copper iodide in combination with DMEDA and Cs2CO3 to provide a wide range of N-aryla