1335195-73-7Relevant articles and documents
Stereodynamics and absolute configuration of stereolabile atropisomers in 2,2-dimethyl-1-aryl-1-indanols
Casarini, Daniele,Mancinelli, Michele,Mazzanti, Andrea,Boschi, Francesca
experimental part, p. 768 - 778 (2012/01/13)
We describe herein the investigation of the stereodynamic processes occurring in a series of 1-aryl-2,2-dimethylindanols, by dynamic NMR. When the aryl moiety is a mesityl or a 2-methyl-1-naphthyl, the rotational barrier exceeds the 25 kcal/mol, so that s