133545-90-1

Basic information

• Product Name: 2-<2-(cyclohex-1-ene-1-yl)prop-2-ene-1-yl>-2-methylcyclopentane-1,3-dione
• Synonyms: 2-<2-(cyclohex-1-ene-1-yl)prop-2-ene-1-yl>-2-methylcyclopentane-1,3-dione
• CAS NO: 133545-90-1
• Molecular Weight: 232.323
• Mol File: 133545-90-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-<2-(cyclohex-1-ene-1-yl)prop-2-ene-1-yl>-2-methylcyclopentane-1,3-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-<2-(cyclohex-1-ene-1-yl)prop-2-ene-1-yl>-2-methylcyclopentane-1,3-dione(133545-90-1)
• EPA Substance Registry System: 2-<2-(cyclohex-1-ene-1-yl)prop-2-ene-1-yl>-2-methylcyclopentane-1,3-dione(133545-90-1)

Safety Data

• Hazardous Substances Data: 133545-90-1(Hazardous Substances Data)

Upstream product

• 2044-08-8 1-bromocyclohex-1-ene 
• 463-49-0 1,2-propanediene 
• 112208-96-5 C₆H₇O₂^(1-) 
• 765-69-5 2-Methylcyclopentane-1,3-dione 
• 28075-50-5 cyclohex-1-en-1-yl trifluoromethane sulfonate 

Downstream Products

• 133545-97-8 2-[2-Cyclohex-2-en-(Z)-ylidene-propyl]-2-methyl-cyclopentane-1,3-dione 

Relevant articles and documents

Use of carbonallation of allenes in the synthsis of polycyclic compound. A rapid access to steroid skeletons

The carbonallation of allenes in the presence of a 1,3-cycloalkanedione enolete leads, in certain cases with good yields, to 2-substituted 1,3-cycloalkanediones with an unsaturated chain with a 1,3-butadienyl moiety (compounds 1). Under acidic conditions, these compounds can be readily cyclized with the formation of a cyclohexane ring if the substituents of the butadienyl framework exert sufficient stabilization on the electrodeficient carbon of the transition state. This methodology leads in a two-step sequence to steroids with an aromatic A-ring. Elsevier,.