133577-98-7

Basic information

• Product Name: (3S,4S)-1,6-Diphenyl-hexane-3,4-diol
• Synonyms: (3S,4S)-1,6-Diphenyl-hexane-3,4-diol
• CAS NO: 133577-98-7
• Molecular Weight: 270.371
• Mol File: 133577-98-7.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: (3S,4S)-1,6-Diphenyl-hexane-3,4-diol(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S)-1,6-Diphenyl-hexane-3,4-diol(133577-98-7)
• EPA Substance Registry System: (3S,4S)-1,6-Diphenyl-hexane-3,4-diol(133577-98-7)

Safety Data

• Hazardous Substances Data: 133577-98-7(Hazardous Substances Data)

Upstream product

• 1589-82-8 phenylmagnesium bromide 
• 298-18-0 (S,S)-diepoxybutane 
• 6738-06-3 phenylethynylmagnesium bromide 
• 2579-22-8 Phenylpropargyl aldehyde 
• 104-53-0 3-phenyl-propionaldehyde 
• 17592-47-1 meso-1,6-diphenyl-hexa-1,5-diyne-3,4-diol 

Relevant articles and documents

Reductive self-coupling reaction of imines and aldehydes induced by strontium metal

Aromatic aldimines reacted with Sr in the presence of a catalytic amount of iodine to give self-coupling products in good yields, whereas aromatic and aliphatic aldehydes underwent a similar reaction effected by the combined use of Sr and Al(OEt)3. Copyright

dl-SElective pinacol-type coupling using zinc, chlorosilane, and catalytic amounts of Cp2VCl2; dl-1,2-dicyclohexylethanediol: (1,2-ethanediol,1,2-dicyclohexyl-)

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Efficient diastereoselective pinacol reaction of aliphatic and aromatic aldehydes by combined use of newly utilized titanium(II) bromide and copper

Newly utilized low-valent titanium reductant, titanium(II) bromide, was conveniently prepared by treating titanium(IV) bromide with hexamethyldisilane. The pinacol reaction of aromatic and aliphatic aldehydes including primary aldehydes proceeded smoothly in dichloromethane-pivalonitrile at temperatures ranging from -23 to 0 °C by the combined use of soluble titanium(II) bromide and copper to give 1,2-diols in good to high yields with good to high dl-selectivities.