133604-09-8

Basic information

• Product Name: (2R,3S,4S,5S,6S)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-5-vinylnonadecane-1,2,3,6-tetrol
• Synonyms: (2R,3S,4S,5S,6S)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-5-vinylnonadecane-1,2,3,6-tetrol
• CAS NO: 133604-09-8
• Molecular Weight: 502.778
• Mol File: 133604-09-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S,4S,5S,6S)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-5-vinylnonadecane-1,2,3,6-tetrol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4S,5S,6S)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-5-vinylnonadecane-1,2,3,6-tetrol(133604-09-8)
• EPA Substance Registry System: (2R,3S,4S,5S,6S)-3-O-benzyl-1,2-O-isopropylidene-4-methyl-5-vinylnonadecane-1,2,3,6-tetrol(133604-09-8)

Safety Data

• Hazardous Substances Data: 133604-09-8(Hazardous Substances Data)

Upstream product

• 124-25-4 myristylaldehyde 
• 128632-65-5 (R)-4-((E)-(1S,2S)-1-Benzyloxy-5-bromo-2-methyl-pent-3-enyl)-2,2-dimethyl-[1,3]dioxolane 
• 100572-69-8 (2R,3S,4S)-3-Bnzyloxy-1,2-O-isopropylidene-4-methyl-5-hexene-1,2-diol 
• 120040-77-9 (2R,3S)-3-Benzyloxy-3-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-propionaldehyde 
• 133604-42-9 (E)-(4S,5S)-5-Benzyloxy-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methyl-pent-2-enoic acid ethyl ester 
• 133604-43-0 (E)-(4S,5S)-5-Benzyloxy-5-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-4-methyl-pent-2-en-1-ol 

Downstream Products

• 133604-23-6 (2R,3S,4S,5S,6S)-3-O-benzyl-4-methyl-5-vinylnonadecane-1,2,3,6-tetrol 

Relevant articles and documents

Highly Felkin-Anh Selective Hiyama Additions of Chiral Allylic Bromides to Aldehydes. Application to the First Synthesis of Nephromopsinic Acid and Its Enantiomer

The chromium(II)-mediated addition ("Hiyama reaction") of the chiral allylic bromides 13, 15, 19, 22, 24, and 27 to achiral and chiral aldehydes proceeds with high Felkin-Anh selectivity with respect to the stereocenter at Cγ in the bromide (Table II). By