133618-79-8

Basic information

• Product Name: methyl 4-amino-5-benzhydrylideneamino-3,3-dimethylcyclopenta-1,4-dienecarboxylate
• Synonyms: methyl 4-amino-5-benzhydrylideneamino-3,3-dimethylcyclopenta-1,4-dienecarboxylate
• CAS NO: 133618-79-8
• Molecular Weight: 346.429
• Mol File: 133618-79-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 4-amino-5-benzhydrylideneamino-3,3-dimethylcyclopenta-1,4-dienecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 4-amino-5-benzhydrylideneamino-3,3-dimethylcyclopenta-1,4-dienecarboxylate(133618-79-8)
• EPA Substance Registry System: methyl 4-amino-5-benzhydrylideneamino-3,3-dimethylcyclopenta-1,4-dienecarboxylate(133618-79-8)

Safety Data

• Hazardous Substances Data: 133618-79-8(Hazardous Substances Data)

Upstream product

• 70591-20-7 N-(diphenylmethylene)aminoacetonitrile 
• 70335-50-1 methyl (E)-4-bromo-4-methylpenten-2-oate 

Relevant articles and documents

Allylic substitution by carbon nucleophiles on γ-bromo-α,β-unsaturated esters: competition with Michael induced ring closure

In THF, the reaction of lithiated aryl aceto- and propiononitriles or diphenylmethyleneacetonitrile with γ-bromo-α,β-unsaturated tertiary ester 1a does not give cyclopropanes but a SN' type allylic substitution.On the other hand, phenylacetates enolates a