133619-06-4

Basic information

• Product Name: (1R)-1-(1-dimethylphenylsilyl-4-benzyloxy-2-butene) (2R)-2-O-acetyl-2-phenylacetate
• Synonyms: (1R)-1-(1-dimethylphenylsilyl-4-benzyloxy-2-butene) (2R)-2-O-acetyl-2-phenylacetate
• CAS NO: 133619-06-4
• Molecular Weight: 488.656
• Mol File: 133619-06-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R)-1-(1-dimethylphenylsilyl-4-benzyloxy-2-butene) (2R)-2-O-acetyl-2-phenylacetate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R)-1-(1-dimethylphenylsilyl-4-benzyloxy-2-butene) (2R)-2-O-acetyl-2-phenylacetate(133619-06-4)
• EPA Substance Registry System: (1R)-1-(1-dimethylphenylsilyl-4-benzyloxy-2-butene) (2R)-2-O-acetyl-2-phenylacetate(133619-06-4)

Safety Data

• Hazardous Substances Data: 133619-06-4(Hazardous Substances Data)

Upstream product

• 3839-31-4 dimethyl(phenyl)silyllithium 
• 69152-87-0 4-benzyloxycrotonaldehyde 
• 51019-43-3 (R)-(-)-O-acetylmandelic acid 
• 133618-96-9 (E)-1-(phenyldimethylsilyl)-4-(benzyloxy)-but-2-en-1-ol 

Downstream Products

• 133696-51-2 (R)-(E)-4-(Benzyloxy)-1-(dimethylphenylsilyl)but-2-en-1-ol 

Relevant articles and documents

Synthesis, resolution and absolute stereochemical assignment of C1-oxygenated allylsilanes and C3-oxygenated vinylsilanes

(R)-O-acetyl mandelic acid has been utilized for the development of a procedure for resolution and absolute stereochemical assignment of C1-oxygenated E-crotylsilanes 1a-c. The procedure is enhanced further by an efficient boron trifluoride etherate catal