1337877-10-7

Basic information

• Product Name: 5-(benzenesulfonyl)-1-{[(tert-butyldimethylsilyl)oxy]methyl}-4-(cyclopent-3-en-1-yloxy)cyclohexa-2,4-dien-1-ol
• Synonyms: 5-(benzenesulfonyl)-1-{[(tert-butyldimethylsilyl)oxy]methyl}-4-(cyclopent-3-en-1-yloxy)cyclohexa-2,4-dien-1-ol
• CAS NO: 1337877-10-7
• Molecular Weight: 462.682
• Mol File: 1337877-10-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5-(benzenesulfonyl)-1-{[(tert-butyldimethylsilyl)oxy]methyl}-4-(cyclopent-3-en-1-yloxy)cyclohexa-2,4-dien-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(benzenesulfonyl)-1-{[(tert-butyldimethylsilyl)oxy]methyl}-4-(cyclopent-3-en-1-yloxy)cyclohexa-2,4-dien-1-ol(1337877-10-7)
• EPA Substance Registry System: 5-(benzenesulfonyl)-1-{[(tert-butyldimethylsilyl)oxy]methyl}-4-(cyclopent-3-en-1-yloxy)cyclohexa-2,4-dien-1-ol(1337877-10-7)

Safety Data

• Hazardous Substances Data: 1337877-10-7(Hazardous Substances Data)

Upstream product

• 62435-72-7 2,5-dimethoxy-2,5-dihydro-furan-2-carboxylic acid methyl ester 
• 1337876-94-4 (tert-butyl)({[5-(cyclopent-3-en-1-yloxy)-furan-2-yl]methoxy})dimethylsilane 
• 1337876-92-2 methyl 5-(cyclopent-3-en-1-yloxy)furan-2-carboxylate 
• 611-13-2 2-furoic acid methyl ester 

Relevant articles and documents

Synthesis of spiroketals under neutral conditions via a type III ring-rearrangement metathesis strategy

A conceptually novel approach to spiro- and dispiroketals of various ring-sizes under neutral conditions has been designed which complements the classical thermodynamically driven tactic. Key steps involved the formation of α-alkoxyfurans, their [4+2] or [4+3] cycloaddition reactions and the ring-rearrangement metathesis of the resulting oxabicycles.