133867-57-9

Basic information

• Product Name: (R)-Phenyl-[(tetrahydro-pyran-2-yloxy)]-acetic acid methyl ester
• Synonyms: (R)-Phenyl-[(tetrahydro-pyran-2-yloxy)]-acetic acid methyl ester
• CAS NO: 133867-57-9
• Molecular Weight: 250.295
• Mol File: 133867-57-9.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (R)-Phenyl-[(tetrahydro-pyran-2-yloxy)]-acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-Phenyl-[(tetrahydro-pyran-2-yloxy)]-acetic acid methyl ester(133867-57-9)
• EPA Substance Registry System: (R)-Phenyl-[(tetrahydro-pyran-2-yloxy)]-acetic acid methyl ester(133867-57-9)

Safety Data

• Hazardous Substances Data: 133867-57-9(Hazardous Substances Data)

Upstream product

• 17199-29-0 (S)-Mandelic acid 
• 110-87-2 3,4-dihydro-2H-pyran 
• 21210-43-5 (S)-Methyl mandelate 
• 158060-53-8 (1R,3R)-1,3-dithiane-1,3-dioxide-2-[(1R)-1-phenyl]methanol 
• 611-71-2 (R)-Mandelic Acid 
• 67-56-1 methanol 
• 157982-25-7 (1R)-tetrahydropyran-(2RS)-2-yl [(1R,3R)-1-(1,3-dithiane-1,3-dioxide-2-yl)-1-phenyl]methyl ether 
• 20698-91-3 (R)-methyl mandelate 
• 100-52-7 benzaldehyde 

Downstream Products

• 60168-63-0 R-(-)-2-phenyl-2-(tetrahydropyranyloxy)ethanol 
• 121917-51-9 (R,R)-(-)-1,11-diphenyl-3,6,9-trioxaundecane-1,11-diol 
• 133811-88-8 (4R,14R)-(-)-4,14-diphenyl-3,6,9,12,15-pentaoxa-21-azabicyclo<15.3.1>heneicosa-1(21),17,19-triene 
• 94199-20-9 (S)-(+)-2-phenyl-2-(tetrahydropyranyloxy)ethanol 
• 109428-31-1 (R)-(-)-2-phenyl-2-(tetrahydropyranyloxy)ethanol 
• 405146-15-8 (1R)-2-(aminooxy)-1-phenylethanol 
• 405146-27-2 3,3-dimethyl-butan-2-one O-(2-hydroxy-2-phenyl-ethyl)-oxime 
• 405146-25-0 1-furan-2-yl-ethanone O-(2-hydroxy-2-phenyl-ethyl)-oxime 
• 405146-23-8 1-furan-2-yl-ethanone O-(2-hydroxy-2-phenyl-ethyl)-oxime 
• 405146-52-3 (1S,2R)-2-((R)-2-Hydroxy-2-phenyl-ethoxyamino)-1-phenyl-propan-1-ol 
• 405146-12-5 2-((R)-2-Hydroxy-2-phenyl-ethoxy)-isoindole-1,3-dione 
• 405146-35-2 (S)-1-Hydroxy-1-phenyl-propan-2-one O-((R)-2-hydroxy-2-phenyl-ethyl)-oxime 

Relevant articles and documents

Asymmetric Radical Reaction in the Coordination Sphere. IV. Ruthenium(II)-Catalyzed Asymmetric Addition of Sulfonyl Chloride to 1-Phenylpropene

The asymmetric addition of methane- and p-toluenesulfonyl chloride to 1-phenylpropene catalyzed by Ru2Cl43 affords optically active 1:1 adducts, (+)-(1R,2RS)-1-chloro-2-methylsulfonyl-1-phenylpropane (2) and (+)-(1R,2RS)-1-chloro-1-phenyl-2-tosy

Zirconium cation coordination in the borohydride-mediated synthesis of β-hydroxy-N-alkoxylamines

Hydride reductions of oxime ethers to hydroxylamine derivatives are facilitated by the participation of neighboring hydroxyl groups. Precomplexation with zirconium cation in ether-methylene chloride solutions is effective for selective C=N bond reduction. The course for stereochemical control is dictated by Lewis acid coordination complexes of E- and Z-oximino ethers which lead to the preferred diastereofacial delivery of external hydride.

Enantioselective Protonation of Samarium Enolates by a C2-Symmetric Chiral Diol

High enantioselectivity (up to 97percentee) have been achieved in the protonation of samarium enolates which were generated by SmI2-mediated cross-coupling reaction between unsymmetrical dialkylketene and allyl iodide, using, using a C2-symmetr