1340343-75-0Relevant articles and documents
A Concise Copper-Catalyzed Oxytrifluoromethylation of Allyl Alcohols
Chen, Longhui,Feng, Xintong,Guo, Minjie,Sun, Qi,Tang, Xiangyang,Wang, Guangwei,Yang, Zequn
, (2021/12/13)
An efficient oxytrifluoromethylation of 1-aryl-substituted allyl alcohols has been developed using Togni's reagent II as a trifluoromethylation reagent and copper(I) chloride as a catalyst. This reaction proceeded through a one-pot process of trifluoromet
Copper-catalysed ring-opening trifluoromethylation of cyclopropanols
He, Xia-Ping,Shu, Yong-Jin,Dai, Jian-Jun,Zhang, Wen-Man,Feng, Yi-Si,Xu, Hua-Jian
, p. 7159 - 7163 (2015/07/01)
A copper-catalysed ring-opening trifluoromethylation reaction of cyclopropanols has been developed. Various β-trifluoromethyl ketones are obtained in good to excellent yields under mild reaction conditions. The present method also exhibits good functional-group compatibility. The mechanism of this new ring-opening trifluoromethylation reaction was investigated by radical trapping reactions.