13407-60-8

Basic information

• Product Name: Methyl 3,6-anhydro-α-D-glucopyranoside
• Synonyms: 1-O-Methyl-3,6-anhydro-α-D-glucopyranose;Methyl 3,6-anhydro-α-D-glucopyranoside
• CAS NO: 13407-60-8
• Molecular Formula: C₇H₁₂O₅
• Molecular Weight: 176.16718
• Mol File: 13407-60-8.mol
• Article Data: 2

Chemical Properties

• Melting Point: 108 °C
• Boiling Point: 378.5±42.0 °C(Predicted)
• Appearance: /
• Density: 1.41±0.1 g/cm3(Predicted)
• PKA: 12.72±0.60(Predicted)
• CAS DataBase Reference: Methyl 3,6-anhydro-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 3,6-anhydro-α-D-glucopyranoside(13407-60-8)
• EPA Substance Registry System: Methyl 3,6-anhydro-α-D-glucopyranoside(13407-60-8)

Safety Data

• Hazardous Substances Data: 13407-60-8(Hazardous Substances Data)

Upstream product

• 7732-18-5 water 
• 345892-40-2 methyl-(O⁶-sulfo-α-D-mannopyranoside) 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 26922-78-1 methyl 2,3-anhydro-4,6-di-O-methylsulphonyl-α-D-allopyranoside 
• 98-88-4 benzoyl chloride 
• 6619-09-6 methyl 6-O-tosyl-α-D-glucopyranoside 

Downstream Products

• 17184-28-0 Methyl-3,6-anhydro-α-D-glucofuranosid 
• 7625-23-2 3,6-anhydro-D-glucose 
• 87595-96-8 Methyl-3,6-anhydro-2,5-di-O-tosyl-α-D-glucofuranosid 
• 137013-08-2 methyl 3,6-anhydro-2,4-di-O-phenoxythiocarbonyl-α-D-glucopyranoside 
• 87638-78-6 3,6-anhydro-D-glucofuranose 
• 17184-28-0 (2S,3R,3aR,6aR)-2-Methoxy-hexahydro-furo[3,2-b]furan-3,6-diol 
• 13059-08-0 Acetic acid (1S,3S,4R,5R,8S)-4-acetoxy-3-methoxy-2,6-dioxa-bicyclo[3.2.1]oct-8-yl ester 
• 13059-08-0 Acetic acid (1S,3S,4R,5R,8R)-4-acetoxy-3-methoxy-2,6-dioxa-bicyclo[3.2.1]oct-8-yl ester 

Relevant articles and documents

Reversed imidazole nucleosides. Alternative pathways of synthesis

The reversed imidazole nucleosides were obtained on three independent routes: a) by the nucleophilic substitution of terminal tosylate group in sugar derivatives with imidazole-1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) salts, b) from monosugar derivatives with unprotected terminal hydroxy group and substituted imidazoles, under the Mitsunobu reactions conditions, c) by the reaction of monosugars possessing terminal primary amino group with 1,4-dinitroimidazoles. Limitations of these routes are discussed.