134317-21-8Relevant articles and documents
Luminescent 1D- and 2D-Coordination Polymers Using CuX Salts (X = Cl, Br, I) and a Metal-Containing Dithioether Ligand
Juvenal, Frank,Langlois, Adam,Bonnot, Antoine,Fortin, Daniel,Harvey, Pierre D.
, p. 11096 - 11109 (2016)
The organometallic synthon trans-[p-MeSC6H4C≡C-Pt(PMe3)2-C≡CC6H4SMe] (L1) reacts with CuX (X = Cl, Br, I) in PrCN and PhCN to form 1D- or 2D-coordination polymers (CP) with a very high degr
Synthesis, Structure and Physical Properties of "wire-like" Metal Complexes
Naher, Masnun,Bock, S?ren,Langtry, Zakary M.,O'Malley, Kieran M.,Sobolev, Alexandre N.,Skelton, Brian W.,Korb, Marcus,Low, Paul J.
, p. 4667 - 4687 (2020)
The syntheses and crystallographically determined structures of metal complexes trans-[M(CCR)2Ln] (MLn = Ru(dppe)2, Ru{P(OEt)3}4, Pt(PEt3)2) featuring acetylide ligands further functionalized by aryl thioether groups are reported, together with those of a
Invisible Silver Guests Boost Order in a Framework That Cyclizes and Deposits Ag3Sb Nanodots
Ahn, Dohyun,Cheng, Shengxian,Feng, Weijin,He, Jun,Hu, Jieying,Xin, Yinger,Xu, Zhengtao,Zeller, Matthias
supporting information, p. 5757 - 5763 (2021/05/04)
The infusion of metal guests into (i.e., metalating) the porous medium of metal-organic frameworks (MOFs) is a topical approach to wide-ranging functionalization purposes. We report the notable interactions of AgSbF6 guests with the designer MOF host ZrL1 [Zr6O4(OH)7(L1)4.5(H2O)4]. (1) The heavy-atom guests of AgSbF6 induce order in the MOF host to allow the movable alkyne side arm to be fully located by X-ray diffraction, but they themselves curiously remain highly disordered and absent in the strucutral model. The enhanced order of the framework can be generally ascribed to interaction of the silver guests with the host alkyne and thioether functions, while the invisible heavy-atom guest represents a new phenomenon in the metalation of open framework materials. (2) The AgSbF6 guests also participate in the thermocyclization of the vicinal alkyne units of the L1 linker (at 450 °C) and form the rare nanoparticle of Ag3Sb supported on the concomitantly formed nanographene network. The resulted composite exhibits high electrical conductivity (1.0 S/cm) as well as useful, mitigated catalytic activity for selectively converting nitroarenes into the industrially important azo compounds, i.e., without overshooting to form the amine side products. The heterogeneous/cyclable catalysis entails only the cheap reducing reagents of NaBH4, ethanol, and water, with yields being generally close to 90%.
Synthesis, Electrochemistry, and Optical Properties of Highly Conjugated Alkynyl-Ferrocenes and -Biferrocenes
Bennett, Troy L. R.,Wilkinson, Luke A.,Lok, Jasmine M. A.,O'Toole, Robert C. P.,Long, Nicholas J.
, p. 1156 - 1162 (2021/05/06)
Sonogashira reactions are utilized herein to react iodo-ferrocenes and -biferrocenes with terminal alkyne ligands, functionalized with both pyridine and thioanisole groups. High-yielding reactions generate both monoalkynyl and dialkynyl derivatives, the r
