1345403-82-8Relevant articles and documents
Copper porphyrin-catalyzed cross dehydrogenative coupling of alkanes with carboxylic acids: Esterification and decarboxylation dual pathway
Chen, Xiao-Yan,Yang, Shuang,Ren, Bao-Ping,Shi, Lei,Lin, Dong-Zi,Zhang, Hao,Liu, Hai-Yang
, (2021/08/13)
A dual-functional copper porphyrin-catalyzed cross dehydrogenative coupling (CDC) of carboxylic acids with alkanes was reported firstly. The reaction gives allylic esters or alkylalkenes depending on the carboxylic acid substrates. Copper porphyrin catalyzed CDC method has the superiority of short reaction time, good functional group tolerance, base and solvent free, producing target products in an atom-economic manner.
Copper porphyrin as efficient catalysts for esterification of allyl sp3 C–H bond with carboxylic acid
Xiong, Ming-Feng,Ali, Atif,Akram, Waseem,Zhang, Hao,Si, Li-Ping,Liu, Hai-Yang
, p. 93 - 97 (2019/04/08)
We described that copper 5,10,15,20-tetrakis (ethoxycarbonyl)porphyrin (TECP) catalyzed oxidative cross dehydrogenative coupling of allyl sp3 C–H bond with acid for the synthesis of allyl esters in a homogeneous system. This reaction proceeded
Bu4NI-catalyzed construction of tert-butyl peresters from alcohols
Zhang, Hui,Dong, Dao-Qing,Hao, Shuang-Hong,Wang, Zu-Li
, p. 8465 - 8468 (2016/02/09)
A new method for the synthesis of tert-butyl peresters directly from available alcohols catalyzed by Bu4NI at room temperature in an aqueous system was developed. Additionally, allylic esters could also be obtained by combing this method and Kharasch-Sosnovsky reaction via a two-step one-pot procedure.