1345824-07-8

Basic information

• Product Name: acetoxy((N-mesyl)methanesulfonamidyl)iodosobenzene
• Synonyms: acetoxy((N-mesyl)methanesulfonamidyl)iodosobenzene
• CAS NO: 1345824-07-8
• Molecular Weight: 435.261
• Mol File: 1345824-07-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: acetoxy((N-mesyl)methanesulfonamidyl)iodosobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: acetoxy((N-mesyl)methanesulfonamidyl)iodosobenzene(1345824-07-8)
• EPA Substance Registry System: acetoxy((N-mesyl)methanesulfonamidyl)iodosobenzene(1345824-07-8)

Safety Data

• Hazardous Substances Data: 1345824-07-8(Hazardous Substances Data)

Upstream product

• 5347-82-0 dimesylamine 
• 3240-34-4 [bis(acetoxy)iodo]benzene 

Downstream Products

• 1414869-26-3 bis[(N-methylsulfonamidyl)]iodosobenzene 
• 1345824-03-4 N,N'-(1-phenylethane-1,2-diyl)bis(N-(methylsulfonyl)methanesulfonamide) 
• 1397689-48-3 N-(methylsulfonyl)-N-(phenylethynyl)methanesulfonamide 
• 1379606-03-7 (E)-N,N'-(4-(p-tolyl)but-3-ene-1,2-diyl)bis(N-(methylsulfonyl)methanesulfonamide) 
• 1379605-98-7 (E)-N,N'-(4-phenylbut-3-ene-1,2-diyl)bis(N-(methylsulfonyl)methanesulfonamide) 

Relevant articles and documents

Defined hypervalent iodine(III) reagents incorporating transferable nitrogen groups: Nucleophilic amination through electrophilic activation

Only I and N: Hypervalent iodine(III) reagents with two reactive I-N single bonds have been isolated for the first time. Their solid-state and solution structures provide evidence for enhanced electrophilicity at iodine and nucleophilic character of the imine. As a result, improved reactivity in amination reactions and unprecedented nitrogen-transfer reactions under metal-free conditions are realized. Copyright

Enantioselective metal-free diamination of styrenes

Metal-free and asymmetric: The first enantioselective diamination of styrenes simply requires a chiral hypervalent iodine(III) reagent as an oxidant and bismesylimide as a nitrogen source (see scheme, Ms=methanesulfonyl). The reaction proceeds under mild conditions and with high enantiomeric excess.