1345976-46-6

Basic information

• Product Name: 2-allyl-4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone
• Synonyms: 2-allyl-4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone
• CAS NO: 1345976-46-6
• Molecular Weight: 238.327
• Mol File: 1345976-46-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-allyl-4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-allyl-4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone(1345976-46-6)
• EPA Substance Registry System: 2-allyl-4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone(1345976-46-6)

Safety Data

• Hazardous Substances Data: 1345976-46-6(Hazardous Substances Data)

Upstream product

• 60739-53-9 4-(tetrahydro-2H-pyran-2-yloxy)cyclohexanone 
• 1471-03-0 allyl propyl ether 
• 24420-11-9 1-allyl-pyrrolidine 

Relevant articles and documents

Hydrogen-bond-activated palladium-catalyzed allylic alkylation via allylic alkyl ethers: Challenging leaving groups

C-O bond cleavage of allylic alkyl ether was realized in a Pd-catalyzed hydrogen-bond-activated allylic alkylation using only alcohol solvents. This procedure does not require any additives and proceeds with high regioselectivity. The applicability of this transformation to a variety of functionalized allylic ether substrates was also investigated. Furthermore, this methodology can be easily extended to the asymmetric synthesis of enantiopure products (99% ee).