134645-47-9Relevant articles and documents
Some Reactions of 3,6-Bis(arylsulfonylimino)-1,2,4,4,5,5-hexachlorocyclohexenes
Avdeenko, A. P.,Yusina, A. L.
, p. 696 - 699 (2007/10/03)
Reduction of 3,6-bis(arylsulfonylimino)-1,2,4,4,5,5-hexachlorocyclohexenes with Zn in CH3COOH or Na2S2O4 results in elimination of two chlorine atoms to give a benzoid structure.A similar effect is produced by dialkyl hydrogen phosphites.Reactions of the title compounds with methanol and primary aromatic amines result in 1,2-addition.Treatment with secondary amines leads to nucleophilic substitution of chlorine at the sp2-hybridized carbon atom.Reactions with trimethylsilyl dialkyl phosphites proceed in two directions: elimination of two chlorine atoms and 1,6-addition followed by hydrolysis of the intermediate adduct.