1346462-88-1Relevant articles and documents
A Convenient Approach To Synthesize o-Carborane-Functionalized Phosphorescent Iridium(III) Complexes for Endocellular Hypoxia Imaging
Li, Xiang,Tong, Xiao,Yan, Hong,Lu, Changsheng,Zhao, Qiang,Huang, Wei
, p. 17282 - 17290 (2016)
The structure–property relationship of carborane-modified iridium(III) complexes was investigated. Firstly, an efficient approach for the synthesis of o-carborane-containing pyridine ligands a–f in high yields was developed by utilizing stable and cheap B10H10(Et4N)2as the starting material. By using these ligands, iridium(III) complexes I–VII were efficiently prepared. In combination with DFT calculations, the photophysical and electrochemical properties of these complexes were studied. The hydrophilic nido-o-carborane-based iridium(III) complex VII showed the highest phosphorescence efficiency (abs.?P=0.48) among known water-soluble homoleptic cyclometalated iridium(III) complexes and long emission lifetime (τ=1.24 μs) in aqueous solution. Both of them are sensitive to O2, and thus endocellular hypoxia imaging of complex VII was realized by time-resolved luminescence imaging (TRLI). This is the first example of applying TRLI in endocellular oxygen detection with a water-soluble nido-carborane functionalized iridium(III) complex.
Fraternal twin iridium hemicage chelates
St-Pierre, Gabriel,Ladouceur, Sebastien,Fortin, Daniel,Zysman-Colman, Eli
, p. 11726 - 11731 (2012/01/04)
The synthesis and complete photophysical characterization of rigidified neutral hemicage iridium complexes are presented. The hemicage ligands were obtained via a modular synthesis, which will facilitate the expansion of future hemicage syntheses. Slight
