1346528-87-7

Basic information

• Product Name: (S)-4-i-propyl-5,5-dimethyl-3-[(RP)-methyl(phenyl)phosphinoyll]oxazolidin-2-one
• Synonyms: (S)-4-i-propyl-5,5-dimethyl-3-[(RP)-methyl(phenyl)phosphinoyll]oxazolidin-2-one
• CAS NO: 1346528-87-7
• Molecular Weight: 295.318
• Mol File: 1346528-87-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-4-i-propyl-5,5-dimethyl-3-[(RP)-methyl(phenyl)phosphinoyll]oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-i-propyl-5,5-dimethyl-3-[(RP)-methyl(phenyl)phosphinoyll]oxazolidin-2-one(1346528-87-7)
• EPA Substance Registry System: (S)-4-i-propyl-5,5-dimethyl-3-[(RP)-methyl(phenyl)phosphinoyll]oxazolidin-2-one(1346528-87-7)

Safety Data

• Hazardous Substances Data: 1346528-87-7(Hazardous Substances Data)

Upstream product

• 157035-77-3 tert-butyl (S)-(2-hydroxy-2,4-dimethylpentan-3-yl)carbamate 
• 644-97-3 Dichlorophenylphosphine 
• 5761-97-7 methyl(phenyl)phosphinic chloride 
• 168297-86-7 (S)-4-isopropyl-5,5-dimethyloxazolidin-2-one 
• 58561-04-9 N-tert-butoxycarbonyl-L-valine methyl ester 
• 6389-79-3 methyl methylphenylphosphinate 
• 2946-61-4 phenylphosphonous acid dimethyl ester 

Downstream Products

• 17045-47-5 (R)-ethyl(methyl)(phenyl)phosphane oxide 
• 168297-86-7 (S)-4-isopropyl-5,5-dimethyloxazolidin-2-one 
• 1346528-88-8 (S)-4-i-propyl-5,5-dimethyl-3-[(SP)-methyl(phenyl)phosphinoyll]oxazolidin-2-one 
• 1346528-99-1 (RP)-nonylmethylphenyl phosphine oxide 
• 37775-91-0 (SP)-(4-t-butylphenyl)methylphenyl phosphine oxide 
• 1346528-94-6 (SP)-(3,5-dimethylphenyl)methylphenyl phosphine oxide 
• 1346528-97-9 (RP)-(pent-1-ene)methylphenyl phosphine oxide 
• 1346528-95-7 (S)-benzo[d][1,3]dioxol-5-yl(methyl)(phenyl)phosphine oxide 
• 1346528-98-0 (RP)-(2-phenylethyl)methylphenyl phosphine oxide 
• 20663-35-8 (S_p)-(2-methoxyphenyl)methylphenylphosphine oxide 
• 1346528-96-8 (S)-(4-fluorophenyl)(methyl)(phenyl)phosphine oxide 
• 153862-20-5 (S)-(4-(dimethylamino)phenyl)(methyl)(phenyl)phosphine oxide 
• 19229-70-0 (S_P)-(-)-(4-methoxyphenyl)methylphenylphosphine oxide 

Relevant articles and documents

Enantioselective preparation of P-chiral phosphine oxides

A highly efficient chiral auxiliary-based strategy for the asymmetric synthesis of P-chiral phosphine oxides in >98:2 er has been developed. The methodology involves the highly stereoselective formation of P-chiral oxazolidinones that then undergo displacement with a variety of Grignard reagents to prepare the desired phosphine oxides.