1346847-79-7

Basic information

• Product Name: C₂₀H₂₈O₃
• Synonyms: C₂₀H₂₈O₃
• CAS NO: 1346847-79-7
• Molecular Weight: 316.441
• Mol File: 1346847-79-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₀H₂₈O₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₂₈O₃(1346847-79-7)
• EPA Substance Registry System: C₂₀H₂₈O₃(1346847-79-7)

Safety Data

• Hazardous Substances Data: 1346847-79-7(Hazardous Substances Data)

Upstream product

• 35822-58-3 2-bromobenzaldehyde diethyl acetal 
• 1256467-59-0 C₁₅H₂₂O₂ 
• 1346848-03-0 C₁₇H₂₂O₂ 
• 3188-13-4 ethyl chloromethyl ether 
• 1379406-64-0 O-tert-butyl-1,2-dichloroenol ether 
• 660820-44-0 2-(2-methylallyl)benzaldehyde 

Relevant articles and documents

Intramolecular [2 + 2] Cycloaddition reactions of alkynyl ether derived ketenes. a convenient synthesis of donor-acceptor cyclobutanes

Mild thermolysis of tert-butyl alkynyl ethers furnishes aldoketenes, which undergo facile [2 + 2] cycloaddition reactions with pendant di- and trisubstituted alkenes. A wide variety of cis-fused cyclobutanones are produced in moderate to high diastereoselectivity and good to excellent yields by this method, and free hydroxyl groups are tolerated in the ene-ynol ether starting materials. Enol-ynol ethers also undergo efficient reaction to produce donor-acceptor cyclobutanes in high yields.