134736-83-7

Basic information

• Product Name: 2-Cyclohexene-1-ethanol, 2,6,6-trimethyl-, (R)-
• CAS NO: 134736-83-7
• Molecular Formula: C11H20O
• Molecular Weight: 168.279
• Mol File: 134736-83-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Cyclohexene-1-ethanol, 2,6,6-trimethyl-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Cyclohexene-1-ethanol, 2,6,6-trimethyl-, (R)-(134736-83-7)
• EPA Substance Registry System: 2-Cyclohexene-1-ethanol, 2,6,6-trimethyl-, (R)-(134736-83-7)

Safety Data

• Hazardous Substances Data: 134736-83-7(Hazardous Substances Data)

Upstream product

• 134736-79-1 (+/-)-2,4,4-Trimethyl-2-cyclohexenyl acetate 
• 134736-78-0 (+/-)-2,4,4-Trimethyl-2-cyclohexen-1-ol 
• 13395-71-6 2,4,4-trimethyl-2-cyclohexenone 
• 134780-17-9 (S)-2,4,4-trimethyl-2-cyclohexen-1-ol 
• 134780-16-8 (R)-2,4,4-trimethyl-2-cyclohexen-1-ol 
• 78-39-7 Triethyl orthoacetate 
• 134736-82-6 Ethyl <(R)-2,6,6-Trimethyl-2-cyclohexenyl>acetate 

Downstream Products

• 134736-85-9 2-<(R)-2,6,6-Trimethyl-2-cyclohexenyl>ethyl cyanide 
• 39721-65-8 (R)-(+)-α-dihydroionone 
• 143658-50-8 methyl 3-methoxycarbonyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenoate 
• 143728-95-4 3-formyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-pentenal 
• 143658-51-9 3-hydroxymethyl-5-(2,6,6-trimethyl-2-cyclohexenyl)-3-penten-1-ol 
• 134736-84-8 2-<(R)-2,6,6-Trimethyl-2-cyclohexenyl>ethyl tosylate 
• 143658-49-5 2-(2,6,6-trimethyl-2-cyclohexenyl)ethanal 

Relevant articles and documents

Asymmetric synthesis of abietane diterpenoids via B-alkyl Suzuki-Miyaura coupling. Formal total asymmetric synthesis of 12-deoxyroyleanone and cryptoquinone

A convergent synthetic strategy for abietane diterpenoids via B-alkyl Suzuki-Miyaura coupling and Lewis acid-mediated cyclization reactions is established. Asymmetric total synthesis of 12-deoxyroyleanone, an antileishmanial diterpene, is described.

Preparative Bioorganic Chemistry, XV. - Preparation of Optically pure 2,4,4-Trimethyl-2-cyclohexen-1-ol, a New and Versatile Chiral Building Block in Terpene Synthesis

Enzymatic hydrolysis of (+/-)-2,4,4-trimethyl-2-cyclohexenyl acetate with pig liver esterase yielded (R)-(+)-2,4,4-trimethyl-2-cyclohexen-1-ol and unchanged (S)-(-)-acetate (S)-3.Enantiomerically pure (S)-2 was converted into (R)-dihydro