134750-68-8

Basic information

• Product Name: (+)-(S)-t-butylsulfonyl p-tolylsulfinyl methane
• CAS NO: 134750-68-8
• Molecular Weight: 274.405
• Mol File: 134750-68-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (+)-(S)-t-butylsulfonyl p-tolylsulfinyl methane(CAS DataBase Reference)
• NIST Chemistry Reference: (+)-(S)-t-butylsulfonyl p-tolylsulfinyl methane(134750-68-8)
• EPA Substance Registry System: (+)-(S)-t-butylsulfonyl p-tolylsulfinyl methane(134750-68-8)

Safety Data

• Hazardous Substances Data: 134750-68-8(Hazardous Substances Data)

Upstream product

• 14094-12-3 tert-butyl methyl sulfone 
• 1517-82-4 (1R,2S,5R,SS)-(-)-menthyl p-toluenesulfinate 

Downstream Products

• 134750-67-7 (S)-1-t-butylsulfonyl-1-p-tolylsulfinylethene 
• 134780-65-7 (1R,4R,5R)-5-(2-Methyl-propane-2-sulfonyl)-5-((S)-toluene-4-sulfinyl)-bicyclo[2.2.1]hept-2-ene 

Relevant articles and documents

Synthesis and Diels Alder Reactions of (+)-(S)-1-t-Butylsulfonyl-1-p-Tolylsulfinylethene, a New Masked Chiral Ketene Equivalent

Enantiomerically pure (+)-(S)s-1-t-butylsulfonyl-1-p-tolylsulfinylethene (1) was easily prepared in three steps from t-butyl methyl sulfone.The catalyzed Diels-Alder reactions of 1 with cyclopentadiene were highly stereoselective.The major adduct was transformed into (+)-(1R,4R)-dehydronorcamphor and (+)-(1R,4S)-2-t-butylsulfonyl-2,5-norbornadiene.