134901-83-0

Basic information

• Product Name: Mn⁽³⁺⁾*C₁₈H₁₀Cl₂N₄O₂^(2-)*N₃^(1-)={Mn(C₁₈H₁₀Cl₂N₄O₂)(N₃)}
• CAS NO: 134901-83-0
• Molecular Weight: 482.167
• Mol File: 134901-83-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Mn⁽³⁺⁾*C₁₈H₁₀Cl₂N₄O₂^(2-)*N₃^(1-)={Mn(C₁₈H₁₀Cl₂N₄O₂)(N₃)}(CAS DataBase Reference)
• NIST Chemistry Reference: Mn⁽³⁺⁾*C₁₈H₁₀Cl₂N₄O₂^(2-)*N₃^(1-)={Mn(C₁₈H₁₀Cl₂N₄O₂)(N₃)}(134901-83-0)
• EPA Substance Registry System: Mn⁽³⁺⁾*C₁₈H₁₀Cl₂N₄O₂^(2-)*N₃^(1-)={Mn(C₁₈H₁₀Cl₂N₄O₂)(N₃)}(134901-83-0)

Safety Data

• Hazardous Substances Data: 134901-83-0(Hazardous Substances Data)

Upstream product

• 19513-05-4 manganese(III) triacetate dihydrate 
• 130995-69-6 1,2-bis(pyridine-2'-carboxamido)-4,5-dichlorobenzene 

Relevant articles and documents

Syntheses, Electrochemistry and Reactivities of Pyridine Amide Complexes of Chromium(III) and Manganese(III)

Reactions of anhydrous CrCl3 with H2bpb and H2bpc in dimethylformamide and manganese(III) acetate with H2bpc in methanol, yielded the respective *xH2O, *H2O and complexes.The electrochemistry of the chromium(III) amide complexes has been studied by cyclic voltammetry.They exhibit reversible oxidation couples with E0 values ranging from 0.28 to 0.80 V vs. ferrocenium-ferrocene.Except for (1-) which has a quasireversible reduction couple at -1.97 V, the electrochemical reductions are irreversible.The complexes ClO4, and have been shown to catalyse olefin epoxidation by iodosobenzene.With , catalytic oxidation of alkanes by PhIO has also been observed.An oxygen-rebound mechanism involving a Mn(V)=O or a Cr(V)=O intermediate is proposed for the PhIO oxidation reactions.