1350460-30-8

Basic information

• Product Name: 5,7-bis(p-cyanophenyl)-8-hydroxyquinoline
• Synonyms: 5,7-bis(p-cyanophenyl)-8-hydroxyquinoline
• CAS NO: 1350460-30-8
• Molecular Weight: 347.376
• Mol File: 1350460-30-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5,7-bis(p-cyanophenyl)-8-hydroxyquinoline(CAS DataBase Reference)
• NIST Chemistry Reference: 5,7-bis(p-cyanophenyl)-8-hydroxyquinoline(1350460-30-8)
• EPA Substance Registry System: 5,7-bis(p-cyanophenyl)-8-hydroxyquinoline(1350460-30-8)

Safety Data

• Hazardous Substances Data: 1350460-30-8(Hazardous Substances Data)

Upstream product

• 84165-50-4 8-benzyloxy-5,7-dibromoquinoline 
• 521-74-4 broxyquinoline 
• 1350460-23-9 8-benzyloxy-5,7-bis(p-cyanophenyl)quinoline 

Relevant articles and documents

Synthesis, characterization and DFT investigation of aluminum complexes of aryl-substituted-8-hydroxyquinoline

New aryl substituted 8-hydroxyquinoline derivatives have been synthesized. The compounds were characterized by 1H, 13C-NMR spectroscopy and mass spectrometry. The aluminum complexes of these derivatives show strong green emission in the range 530-535 nm with high quantum yield compared to the parent tris (8-hydroxyquinolinato)aluminum(III) complex. The structure of the aryl-substituted 8-hydroxyquinoline aluminum complexes in the ground state have been optimized at the B3LYP/6-31G (*) level of theory. The parent 8-hydroxyquinoline has also been examined using this method with the same basis set. A clear correlation between the shortening of the Al-N bond and red shift in the fluorescence emission band was observed. We have also found that substitution at the 5 and 7 position of the 8-hydroxyquinoline ligand cause simultaneous energy lowering of both highest occupied molecular orbital and the lowest unoccupied molecular orbital with the 5, 7-aryl substituted derivatives exhibiting the greatest effect.