13506-93-9Relevant articles and documents
A Selective Synthesis of (E)-Vinylsilanes by Cationic Rhodium Complex-Catalyzed Hydrosilylation of 1-Alkynes and Tandem Hydrosilylation/Isomerization Reaction of Propargylic Alcohols to β-Silyl Ketones
Takeuchi, Ryo,Nitta, Shuichi,Watanabe, Dai
, p. 3045 - 3051 (1995)
(E)-Vinylsilanes were obtained with high selectivities by BF4/2PPh3-catalyzed hydrosilylation of 1-alkynes with triethylsilane.A wide range of 1-alkynes were used.The hydrosilylation of propargylic alcohols with triethylsilane gave (E)-γ-silyl a
The photochemical addition of aldehydes to vinylsilanes
Komarov,Roman,Komarova
, p. 1405 - 1407 (2007/10/12)
The photochemical reaction of aldehydes of various structures with vinyl and allylsilanes have been investigated. A number of features of this reaction has been established and a convenient method for the synthesis of γ-silicon-containing ketones, includi