1350654-29-3

Basic information

• Product Name: 1-(2-(diphenylphosphino)phenyl)piperidine
• Synonyms: 1-(2-(diphenylphosphino)phenyl)piperidine
• CAS NO: 1350654-29-3
• Molecular Weight: 345.424
• Mol File: 1350654-29-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(2-(diphenylphosphino)phenyl)piperidine(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-(diphenylphosphino)phenyl)piperidine(1350654-29-3)
• EPA Substance Registry System: 1-(2-(diphenylphosphino)phenyl)piperidine(1350654-29-3)

Safety Data

• Hazardous Substances Data: 1350654-29-3(Hazardous Substances Data)

Upstream product

• 82212-00-8 1-(2-bromophenyl)piperidine 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 1350654-34-0 1-(2-(diphenylphosphino)phenyl)piperidine palladium(II) dichloride 

Relevant articles and documents

Preparation and application of air-stable P,N-bidentate ligands for the selective synthesis of δ-lactone via the palladium-catalyzed telomerization of 1,3-butadiene with carbon dioxide

Air-stable P,N-bidentate ligands L1-L7 with cyclic secondary amine moieties linked to the benzene rings of triphenylphosphine were designed and prepared. The chelating coordination mode of the P,N-bidentate ligands to the Pd(II) center was confirmed by determining the X-ray structures of the Pd(II) complexes C1 and C2 derived from ligands L1 and L2, respectively. The ligands were used for the selective synthesis of δ-lactone through the palladium (Pd)-catalyzed telomerization of 1,3-butadiene with carbon dioxide. The highest yield (60% with 79% selectivity) was observed using the Pd2(dba) 3/4-(2-(diphenylphosphino)phenyl)morpholine (L2) catalyst system.