13509-36-9

Basic information

• Product Name: Dithiocarbonic acid S,S-diphenyl ester
• Synonyms: Dithiocarbonic acid S,S-diphenyl ester
• CAS NO: 13509-36-9
• Molecular Formula: C₁₃H₁₀OS₂
• Molecular Weight: 246.35
• Mol File: 13509-36-9.mol
• Article Data: 7

Chemical Properties

• Melting Point: 43.0-43.5 °C(Solv: ethanol (64-17-5))
• Boiling Point: 359.4±15.0 °C(Predicted)
• Appearance: /
• Density: 1.28±0.1 g/cm3(Predicted)
• CAS DataBase Reference: Dithiocarbonic acid S,S-diphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Dithiocarbonic acid S,S-diphenyl ester(13509-36-9)
• EPA Substance Registry System: Dithiocarbonic acid S,S-diphenyl ester(13509-36-9)

Safety Data

• Hazardous Substances Data: 13509-36-9(Hazardous Substances Data)

Upstream product

• 75-44-5 phosgene 
• 930-69-8 sodium thiophenolate 
• 13464-19-2 phenyl chlorothioformate 
• 108-98-5 thiophenol 
• 17347-45-4 (bis(phenylthio)methylene)triphenyl-phosphorane 
• 140-89-6 potassium ethyl xanthogenate 
• 62-53-3 aniline 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 2286-39-7 S-Phenyl thiofluoroformate 
• 6213-94-1 trimethylsiloxyethene 
• 1833-53-0 2-(Trimethylsilyloxy)propene 
• 6651-34-9 2-methyl-1-(trimethylsilyloxy)-1-propene 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 24455-23-0 S₁,S₂-Diphenylethanebis(thioate) 

Downstream Products

• 108-98-5 thiophenol 
• 7304-68-9 phenyl N,N-dimethyl(thiocarbamate) 
• 882-33-7 diphenyldisulfane 

Relevant articles and documents

CARBONATE DERIVATIVE PRODUCTION METHOD

The objective of the present invention is to provide a method for producing a carbonate derivative in a safe and efficient manner. The method for producing a carbonate derivative according to the present invention is characterized in comprising irradiating light on a composition containing a C1-4 halogenated hydrocarbon having one or more kinds of halogen atoms selected from the group consisting of a chlorine atom, a bromine atom and an iodine atom, a nucleophilic functional group-containing compound and the specific base in the presence of oxygen.

Concise and Additive-Free Click Reactions between Amines and CF3SO3CF3

Trifluoromethyl trifluoromethanesulfonate has proved to be an excellent reservoir of difluorophosgene and a promising click ligation for amines in the preparation of urea derivatives, heterocycles, and carbamoyl fluorides under metal- and additive-free conditions. The reactions are rapid, efficient, selective, and versatile, and can be performed in benign solvents, giving products in excellent yields with minimal efforts for purification. The characteristics of the reactions meet the requirements of a click reaction. The use of trifluoromethyl trifluoromethanesulfonate as a click reagent is advantageous over other “CO” sources (e.g., TsOCF3, PhCO2CF3, CsOCF3, AgOCF3, and triphosgene) because this reagent is readily accessible; easy to scale up; and highly reactive, even under metal- and additive-free conditions. It is anticipated that CF3SO3CF3 will be increasingly as important as SO2F2 as a click agent in future drug design and development.

DECARBONYLATION DES DITHIOCARBONATES: UNE VOIE D'ACCES GENERALE AUX COMPLEXES BINUCLEAIRES BIS-μ-(S-ALKYL)-HEXACARBONYLEDIFER

Dithiocarbonates R1SC(O)SR2 (IV) react with to afford the bis-μ-(S-alkyl)-hexacarbonyldiiron coordination compounds: I (R1=R2), II (R1R2=bridging hydrocarbon chain) and III (R1*R2) after a double fragmentation pattern accompanied by loss of carbonyl groups.This unexpected reactivity of ligands IV offers a general route to binuclear iron compounds such as I and II.Some reaction intermediates (V) which led to I, have been identified.However the redistribution of S-alkyl groupings which occurs during the complexation of IV (R1*R2) shows that the decarbonylation reaction can follow several pathways.