135092-52-3

Basic information

• Product Name: (R)-2-(4-Chloro-phenoxy)-propionic acid (1S,5R,6S)-bicyclo[3.2.0]hept-2-en-6-yl ester
• CAS NO: 135092-52-3
• Molecular Weight: 292.762
• Mol File: 135092-52-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (R)-2-(4-Chloro-phenoxy)-propionic acid (1S,5R,6S)-bicyclo[3.2.0]hept-2-en-6-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-(4-Chloro-phenoxy)-propionic acid (1S,5R,6S)-bicyclo[3.2.0]hept-2-en-6-yl ester(135092-52-3)
• EPA Substance Registry System: (R)-2-(4-Chloro-phenoxy)-propionic acid (1S,5R,6S)-bicyclo[3.2.0]hept-2-en-6-yl ester(135092-52-3)

Safety Data

• Hazardous Substances Data: 135092-52-3(Hazardous Substances Data)

Upstream product

• 3307-39-9 2-(4-chlorophenoxy)propionic acid 
• 13259-28-4 (rac)-6-endo-bicyclo<3.2.0>hept-2-en-6-ol 
• 13259-28-4 bicyiclo<3.2.0>hept-2-en-6-ol 

Relevant articles and documents

Some Diastereoselective Enzyme-catalysed Esterifications and Interesterifications

The alcohol bicycloheptenol (+/-)-1 or the corresponding acetate (+/-)-5 couple with 2-(p-chlorophenoxy)propionic acid (+/-)-2 using lipases in organic solvents to give the ester bicycloheptenyl 2-(p-chlorophenyl)propionate (R,R)-3 with good/excellent selectivity.Similarly, 2-methoxycyclohexanol (+/-)-6 or the corresponding acetate (+/-)-7 undergo enzyme-induced coupling to the acid (+/-)-2 to form the (R,R,R)-ester 2-methoxycyclohexyl p-chlorophenoxyacetate 8 almost exclusively in a doubly enantioselective process.