1351067-15-6Relevant articles and documents
Room-temperature C-H bond alkynylation by merging cobalt and photocatalysts
Mandal, Rajib,Barsu, Nagaraju,Garai, Bholanath,Das, Abir,Perekalin, Dmitry,Sundararaju, Basker
, p. 12167 - 12170 (2021/11/30)
A new protocol is developed for the mono- and bis-ortho-C-H alkynylation of easily accessible benzamide derivatives using alkynyl bromides at room temperature by merging cobalt and photocatalysts. The diverse reactivity of various alkynyl bromides towards
Nickel-catalyzed direct alkynylation of C(sp2)-H bonds of amides: An "inverse Sonogashira strategy" to ortho-alkynylbenzoic acids
Landge, Vinod G.,Shewale, Chinmay H.,Jaiswal, Garima,Sahoo, Manoj K.,Midya, Siba P.,Balaraman, Ekambaram
, p. 1946 - 1951 (2016/04/05)
Nickel-catalyzed direct alkynylation of C(sp2)-H bonds of amides using commercially available, inexpensive 8-aminoquinoline as a removable bidentate directing group is described. The present ortho-alkynylation has a broad substrate scope, funct
Palladium-catalyzed direct ortho -alkynylation of aromatic carboxylic acid derivatives
Ano, Yusuke,Tobisu, Mamoru,Chatani, Naoto
, p. 354 - 357 (2012/03/09)
The palladium-catalyzed direct alkynylation of C-H bonds in aromatic carboxylic acid derivatives is described. The use of 8-aminoquinoline as a directing group facilitates the alkynylation of an electronically diverse range of C(sp2)-H bonds.
