135145-88-9

Basic information

• Product Name: 1-C-(2-methylphenyl)-3,4,6-tri-O-(triisopropylsilyl)-D-glucal
• Synonyms: 1-C-(2-methylphenyl)-3,4,6-tri-O-(triisopropylsilyl)-D-glucal
• CAS NO: 135145-88-9
• Molecular Weight: 705.298
• Mol File: 135145-88-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-C-(2-methylphenyl)-3,4,6-tri-O-(triisopropylsilyl)-D-glucal(CAS DataBase Reference)
• NIST Chemistry Reference: 1-C-(2-methylphenyl)-3,4,6-tri-O-(triisopropylsilyl)-D-glucal(135145-88-9)
• EPA Substance Registry System: 1-C-(2-methylphenyl)-3,4,6-tri-O-(triisopropylsilyl)-D-glucal(135145-88-9)

Safety Data

• Hazardous Substances Data: 135145-88-9(Hazardous Substances Data)

Upstream product

• 615-37-2 ortho-methylphenyl iodide 
• 131216-78-9 1,5-anhydro-2-desoxy-3,4,6-tri-O-triisopropylsilyl-D-arabino-hex-1-enitol 
• 131216-80-3 1,5-anhydro-2-desoxy-3,4,6-tri-O-triisopropylsilyl-1-(tri-n-butyl-stannyl)-D-arabino-hex-1-enitol 
• 84109-17-1 2-methylphenylzinc chloride 
• 135145-81-2 3,4,6-tri-O-triisopropylsilyl-1-iodo-D-glucal 

Relevant articles and documents

Preparation of C-Aryl Glucals via the Palladium-Catalyzed Coupling of Metalated Aromatics with 1-Iodo-3,4,6-tri-O-(triisopropylsilyl)-D-glucal

The preparation of the novel iodo glucal 5 from 3,4,6-tri-O-(triisopropylsilyl)-D-glucal (4), via a two-step procedure involving C1 stannylation and subsequent tin-iodine exchange, is described.The palladium-catalyzed coupling of 5 with a variety of metal

The preparation of C-aryl glucals via palladium-catalyzed cross-coupling methods

The C-aryl glucals 17-31 have been prepared by the palladium-catalyzed cross coupling of 1-tributylstannyl-3,4,6-tri-O-(tert-butyldimethylsilyl)-b-glucal (11) and aryl bromides. The major by-product in all of these reactions is the dimer 33, the product o