1351791-42-8Relevant articles and documents
Application of a chiral metal-organic framework in enantioselective separation
Padmanaban, Mohan,Mueller, Philipp,Lieder, Christian,Gedrich, Kristina,Gruenker, Ronny,Bon, Volodymyr,Senkovska, Irena,Baumgaertner, Sandra,Opelt, Sabine,Paasch, Silvia,Brunner, Eike,Glorius, Frank,Klemm, Elias,Kaskel, Stefan
, p. 12089 - 12091 (2011/12/16)
A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal-organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported. The Royal Society of Chemistry 2011.