135191-48-9

Basic information

• Product Name: 2-Hexanol, 6-(phenylthio)-, (S)-
• CAS NO: 135191-48-9
• Molecular Formula: C12H18OS
• Molecular Weight: 210.34
• Mol File: 135191-48-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-Hexanol, 6-(phenylthio)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexanol, 6-(phenylthio)-, (S)-(135191-48-9)
• EPA Substance Registry System: 2-Hexanol, 6-(phenylthio)-, (S)-(135191-48-9)

Safety Data

• Hazardous Substances Data: 135191-48-9(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 16088-62-3 (S)-Propylene oxide 
• 109-49-9 5-Hexen-2-one 
• 172419-22-6 6-Phenylsulfanyl-hexan-2-one 

Downstream Products

• 88526-08-3 (S)-(+)-6-(phenylsulfonyl)-2-hexanol 

Relevant articles and documents

Applications of highly enantioenriched alcohols bearing a phenylthio group in the preparation of ring compounds. The two-pot synthesis of an enantiopure spiroacetal pheromone bearing three chiral centers

The new chiron (S)-6-phenylthio-2-hexanol (3) was prepared in high enantiomeric excess by baker's yeast reduction of the corresponding ketone. Enantioenriched alcohols 1, 2 and 3, prepared previously by a similar procedure, or their racemic counterparts, were transformed into ring closed compounds 5-methyl-2-(phenylthio)tetrahydrofuran (9), 6-methyl-2- (phenylthio)tetrahydropyran (10), 2-methyl-1-phenylsulfonyl cyclopropane (14), cyclobutane (15), cyclopentane (16), and a bee pheromone, (2S,6R,8S)- 2,8-dimethyl-1,7-dioxaspiro[5.5]undecane (20).