13534-08-2

Basic information

• Product Name: Bicyclo<3.3.1>nonadion-(2.6)-bis-(p-toluolsulfonylhydrazon)
• CAS NO: 13534-08-2
• Molecular Weight: 488.632
• Mol File: 13534-08-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Bicyclo<3.3.1>nonadion-(2.6)-bis-(p-toluolsulfonylhydrazon)(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo<3.3.1>nonadion-(2.6)-bis-(p-toluolsulfonylhydrazon)(13534-08-2)
• EPA Substance Registry System: Bicyclo<3.3.1>nonadion-(2.6)-bis-(p-toluolsulfonylhydrazon)(13534-08-2)

Safety Data

• Hazardous Substances Data: 13534-08-2(Hazardous Substances Data)

Upstream product

• 16473-11-3 bicyclo[3.3.1]nonane-2,6-dione 
• 1576-35-8 toluene-4-sulfonic acid hydrazide 
• 16473-11-3 bicyclo[3.3.1]nonane-2,6-dione 

Downstream Products

• 280-65-9 bicyclo[3.3.1]nonane 
• 78127-60-3 N-Benzyl-2-azaadamantane-anti-4,8-diol 
• 78127-61-4 N-Phenyl-2-azaadamantane-anti-4,8-diol 
• 768-41-2 2-Azaadamantane 

Relevant articles and documents

A General Synthesis of N-Substituted 2-Azaadamantanes and Their 4,8-Disubstituted Derivatives

A general synthesis of N-substituted 2-azaadamantanes (1) is reported, along with the corresponding 4,8-dihydroxy derivatives (2).The synthesis offers the advantage of the use of inexpensive and readily available starting material.Dione 3, obtained by decarboxylation of Meerwein's ester, is converted to diene 4 by Bamford-Stevens-type elimination of the corresponding ditosylhydrazone.Epoxidation of 4 affords diepoxide 12, which reacts with primary amines to form the 2-azaadamantyl skeleton 2.Removal of the hydroxyl groups to give 1 is accomplished by using SOCl2 and then LiAlH4.