135388-81-7

Basic information

• Product Name: Benzenamine, N-[diphenyl(phenylimino)ethylidene]-4-methyl-
• CAS NO: 135388-81-7
• Molecular Formula: C27H22N2
• Molecular Weight: 374.485
• Mol File: 135388-81-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-[diphenyl(phenylimino)ethylidene]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-[diphenyl(phenylimino)ethylidene]-4-methyl-(135388-81-7)
• EPA Substance Registry System: Benzenamine, N-[diphenyl(phenylimino)ethylidene]-4-methyl-(135388-81-7)

Safety Data

• Hazardous Substances Data: 135388-81-7(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 78604-82-7 α-p-toluidino-deoxybenzoin 
• 106-49-0 p-toluidine 
• 5722-91-8 1,2-diphenyl-2-(phenylamino)ethanone 
• 13288-66-9 C₂₂H₁₇NOS 
• 586-96-9 Nitrosobenzene 

Relevant articles and documents

Cycloaddition of Nitroso Dipolarophiles to Thiazolium-4-olates. Part 1. Nitrosobenzene and 1-Chloro-1-nitrosocyclohexane

Thiazolium-4-olates 1 and nitrosobenzene participated in regiospecific cycloadditions which gave 3-oxa-2,5-diaza-7-thiatrinorbornan-6-ones 5.On storage, compounds 5 rearranged to the azetobenzothiazine S-oxides 7, fragmented to the benzil diimides 8, and a lost sulfur atom to give the iminoimides 9.The cycloadditions of mesoionic compounds 1 with 1-chloro-1-nitrosocyclohexane exhibited a reversed regiochemistry and formed the trinorbornanes 6, which were subsequently attacked by nucleophiles at the bridgehead to produce the thiazolones 14.The mechanisms of formation of all the products are discussed.Structures 7a and 14d were confirmed by single-crystal X-ray analyses.