135426-11-8Relevant articles and documents
X-ray crystallography and magnetic studies of a stable macrocyclic tetranitroxide. Intramolecular dimer of nitroxides in a constrained geometry of the upper rim of calix[4]arene
Rajca, Andrzej,Pink, Maren,Rojsajjakul, Teerapat,Lu, Kan,Wang, Hua,Rajcat, Suchada
, p. 8534 - 8538 (2003)
Synthesis, crystallography, and magnetic characterization of a stable macrocyclic tetranitroxide 1, a calix[4]arene, which is functionalized with four tert-butylnitroxides at the upper rim, is described. In solution, 1 has a 4-fold symmetric fixed cone co
Calixarenes. 25. Conformations and Structures of the Products of Arylmethylation of Calixarenes
Gutsche, C. David,Reddy, P. Amruta
, p. 4783 - 4791 (2007/10/02)
The arylmethylations of calixarenes reported in this paper serve as companion pieces to an earlier study of the effects of reaction conditions and the structure of the derivatizing agent on the conformational outcome of the aroylation of calixarenes.In contrast to the aroylation reaction, where a significant and predictable relation is observed between the para substituent of the aroyl chloride and the ratio of conformers formed, the arylmethylation reaction shows only a small and much less easily predictable dependence of the conformer ratio on the para substituent of the arylmethyl halide.Also, whereas the products of aroylation are the cone and/or 1,3-alternate conformers, those of arylmethylation are the cone and/or partial cone conformers.While no rationale has yet emerged to explain this difference, a study of the benzylation of dibenzyl and tribenzyl ethers of 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrahydroxycalixarene has established that the conformations of the tetraethers are not completely established until the third step in some cases and the fourth step in others.