1354629-79-0

Basic information

• Product Name: (2S,3R)-3-methyl-2-phenylhex-4-enoic acid
• CAS NO: 1354629-79-0
• Molecular Weight: 204.269
• Mol File: 1354629-79-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2S,3R)-3-methyl-2-phenylhex-4-enoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R)-3-methyl-2-phenylhex-4-enoic acid(1354629-79-0)
• EPA Substance Registry System: (2S,3R)-3-methyl-2-phenylhex-4-enoic acid(1354629-79-0)

Safety Data

• Hazardous Substances Data: 1354629-79-0(Hazardous Substances Data)

Upstream product

• 103-82-2 phenylacetic acid 
• 85217-71-6 methyl (3E)-pent-3-en-2-yl carbonate 

Relevant articles and documents

Palladium-catalyzed allylic alkylation of doubly deprotonated carboxylic acids

Doubly deprotonated carboxylic acids undergo smooth palladium-catalyzed carbon alkylations with the allylic substrates methyl allyl carbonate and (E)-methyl (pent-3-en-2-yl) carbonate to give γ,δ-unsaturated carboxylic acids. A diastereoselective and enantioselective protocol leads to (2S,3R)-hexenoic acid in 87% ee. Copyright