135491-07-5

Basic information

• Product Name: 4,4,7,7-tetraphenyl-4,7-diphosphonia-1,10-decadioic acid dichloride
• CAS NO: 135491-07-5
• Molecular Weight: 615.473
• Mol File: 135491-07-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4,4,7,7-tetraphenyl-4,7-diphosphonia-1,10-decadioic acid dichloride(CAS DataBase Reference)
• NIST Chemistry Reference: 4,4,7,7-tetraphenyl-4,7-diphosphonia-1,10-decadioic acid dichloride(135491-07-5)
• EPA Substance Registry System: 4,4,7,7-tetraphenyl-4,7-diphosphonia-1,10-decadioic acid dichloride(135491-07-5)

Safety Data

• Hazardous Substances Data: 135491-07-5(Hazardous Substances Data)

Upstream product

• 107-94-8 chloropropionic acid 
• 1663-45-2 1,2-bis-(diphenylphosphino)ethane 

Downstream Products

• 135491-11-1 1,2-ethanediyl-bis(diphenylphosphonio-3-propionate) 

Relevant articles and documents

Preparation and Properties of ω-Phosphino-phosphoniocarboxylic Acids and their Betaines

In an attempt to provide phosphorus analogues of aminocarboxylic acids and their betaines, α,ω-bis(diphenylphosphino)alkanes (dppm, dppe, dppp, dppb) were converted into ω-phosphino-phosphoniocarboxylates and diphosphonio-biscarboxylates.While the reactions with haloacetic acids or haloacetates only lead to methylphosphonium derivatives owing to decarboxylation of the intermediates, β-chloropropionic acids converts Ph2P(CH2)nPPh2 compounds into the target products Ph2PCH2PPh2+(CH2)2COOHCl- (1) and CH22*2Cl- (2), for n = 1.For n = 2, 3 and 4, only the analogues of 2 could be prepared (3-5).Treatment of 1 and 2 with sodium bicarbonate afforded the corresponding betaines Ph2PCH2PPh2+CH2CH2COO- (isolated as a dihydrate 6) and CH2+CH2CH2COO->2 (isolated as the tetrahydrate 7).