135509-09-0

Basic information

• Product Name: [1-Benzo[1,3]dioxol-5-yl-meth-(E)-ylidene]-(3,4-dimethoxy-benzyl)-amine
• CAS NO: 135509-09-0
• Molecular Weight: 299.326
• Mol File: 135509-09-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [1-Benzo[1,3]dioxol-5-yl-meth-(E)-ylidene]-(3,4-dimethoxy-benzyl)-amine(CAS DataBase Reference)
• NIST Chemistry Reference: [1-Benzo[1,3]dioxol-5-yl-meth-(E)-ylidene]-(3,4-dimethoxy-benzyl)-amine(135509-09-0)
• EPA Substance Registry System: [1-Benzo[1,3]dioxol-5-yl-meth-(E)-ylidene]-(3,4-dimethoxy-benzyl)-amine(135509-09-0)

Safety Data

• Hazardous Substances Data: 135509-09-0(Hazardous Substances Data)

Upstream product

• 120-57-0 piperonal 
• 5763-61-1 3,4-dimethoxybenzylamine 

Downstream Products

• 135509-01-2 (3R,4S)-3-(4-Allyl-2-methoxy-phenoxy)-4-benzo[1,3]dioxol-5-yl-1-(3,4-dimethoxy-benzyl)-azetidin-2-one 
• 135508-96-2 (3S,4R)-4-Benzo[1,3]dioxol-5-yl-1-(3,4-dimethoxy-benzyl)-3-phenoxy-azetidin-2-one 
• 328002-39-7 N-(3,4-dimethoxybenzyl)piperonylamine 
• 135509-00-1 (3R,4S)-4-Benzo[1,3]dioxol-5-yl-1-(3,4-dimethoxy-benzyl)-3-((1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyloxy)-azetidin-2-one 
• 135509-02-3 (3R,4S)-4-Benzo[1,3]dioxol-5-yl-1-(3,4-dimethoxy-benzyl)-3-(2-isopropyl-5-methyl-phenoxy)-azetidin-2-one 

Relevant articles and documents

Synthesis of 7,12-dihydro-12-phenyl-5H-6,12-methanodibenz[cf]azocines via N,N-dibenzylphenacylamines

N,N-DibenzyIphenacylamines (1) were prepared in high yields by a onepot reaction and cyclized at room temperature to give 7,12-dihydro-12-phenyl-5H-6,12-methanodibenz[cf]azocines in high yields. 95% H2SO4 or 70% HClO4 was used as cyclization catalysts. The double-cyclization proceeds smoothly in the cases where electron-donating groups are present in both benzene ring. N-2,3-dimethoxybenzyl-N-benzylphenacylamine (If) gave the corresponding N-benzyl-1,2-dihydro-4-phenylisoquinoline on treatment with 95% H2SO4 while N-3,4-Dimethoxybenzyl-N-benzylphenacylamine (1a) at the same reaction conditions and reaction time cyclized to the corresponding dibenzazocine. However la gave the corresponding dihydroisoquinoline which disproportionates to give N-benzyl-1,2,3,4-tetrahydro-4-phenylisoquinoline and N-benzyl-4-phenylisoquinolinium when treated with 70% perchloric acid at room temperature.