1356012-59-3

Basic information

• Product Name: cycloprop-2-ene-1,1-diyldicyclohexane
• Synonyms: cycloprop-2-ene-1,1-diyldicyclohexane
• CAS NO: 1356012-59-3
• Molecular Weight: 204.356
• Mol File: 1356012-59-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: cycloprop-2-ene-1,1-diyldicyclohexane(CAS DataBase Reference)
• NIST Chemistry Reference: cycloprop-2-ene-1,1-diyldicyclohexane(1356012-59-3)
• EPA Substance Registry System: cycloprop-2-ene-1,1-diyldicyclohexane(1356012-59-3)

Safety Data

• Hazardous Substances Data: 1356012-59-3(Hazardous Substances Data)

Upstream product

• 1356012-67-3 1,1-dibromo-2,2-dicyclohexylcyclopropane 
• 1356012-69-5 1-bromo-2,2-dicyclohexylcyclopropane 
• 119-60-8 dicyclohexyl ketone 
• 57013-04-4 ethene-1,1-diyldicyclohexane 

Downstream Products

• 1393672-46-2 (E)-(3,3-dicyclohexylprop-1-enyl)(phenyl)sulfane 
• 1393672-27-9 S-(3,3-dicyclohexylprop-2-en-1-yl)benzenecarbothioate 
• 1415087-92-1 C₂₂H₃₀OS 
• 1356012-43-5 3-(3,3-dicyclohexylallyl)-5-methoxy-1H-indole 
• 1356012-49-1 3,3'-(3,3-dicyclohexylprop-2-ene-1,1-diyl)bis(5-methoxy-1H-indole) 
• 1356012-51-5 3,3'-((3,3-dicyclohexyloxiran-2-yl)methylene)bis(5-methoxy-1H-indole) 
• 1356012-55-9 3,3'-(3,3-dicyclohexylprop-2-ene-1,1-diyl)bis(5-fluoro-1H-indole) 
• 1356012-56-0 3,3'-((3,3-dicyclohexyloxiran-2-yl)methylene)bis(5-fluoro-1H-indole) 
• 1356012-53-7 3,3'-(3,3-dicyclohexylprop-2-ene-1,1-diyl)bis(1H-indole) 
• 1356012-54-8 3,3'-((3,3-dicyclohexyloxiran-2-yl)methylene)bis(1H-indole) 
• 1356012-23-1 C₂₃H₃₁N 

Relevant articles and documents

Synthesis of Functionalized α-Vinyl Aldehydes from Enaminones

An efficient RhII-catalyzed synthesis of functionalized α-vinyl aldehydes with high E/Z stereoselectivity was developed. The reaction mediates the cyclopropanation of enaminones with vinyl carbenoids that are generated from cyclopropenes in situ to give the aminocyclopropane intermediates. Selective C?C bond cleavage of the cyclopropane intermediates leads to formation of α-vinyl aldehyde derivatives with high E/Z selectivity. This method proceeds at room temperature under very mild reaction conditions and works with a broad substrate scope.

Divergent outcomes of gold(I)-catalyzed indole additions to 3,3-disubstituted cyclopropenes

Depending on the conditions employed, gold(I)-catalyzed addition of indoles to 3,3-disubstituted cyclopropenes can be controlled to yield either 3-(E)-vinylindoles (3) or bis-indolylalkanes (4). If the cyclopropene substituents are sterically bulky, unprecedented gold-catalyzed oxidation under air occurs to yield bis-indolylalkene (5) and epoxide (6) at room temperature.