135625-69-3Relevant articles and documents
A Short, Chirospecific Synthesis of the Ant Venom Alkaloid (3R,5S,8S)-3,5-Dialkylpyrrolizidines
Takahata, Hiroki,Bandoh, Hiroshi,Momose, Takefumi
, p. 4401 - 4404 (2007/10/02)
The stereospecific synthesis of both (+)-xanovenine (1) and (+)-(3R,5S,8S)-3-methyl-5-(8-nonenyl)pyrrolizidine (2) found in ant venom, is described.The stereoselective intramolecular amidomercuration of the N-alkenylurethane 3, available from D-alanine, f