135638-23-2

Basic information

• Product Name: <2R-(2a(1R*,2S*),3aα,4α,7α,7aα)>-2-<(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-1-phenylbutan-1-ol
• Synonyms: <2R-(2a(1R*,2S*),3aα,4α,7α,7aα)>-2-<(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-1-phenylbutan-1-ol
• CAS NO: 135638-23-2
• Molecular Weight: 344.494
• Mol File: 135638-23-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: <2R-(2a(1R*,2S*),3aα,4α,7α,7aα)>-2-<(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-1-phenylbutan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: <2R-(2a(1R*,2S*),3aα,4α,7α,7aα)>-2-<(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-1-phenylbutan-1-ol(135638-23-2)
• EPA Substance Registry System: <2R-(2a(1R*,2S*),3aα,4α,7α,7aα)>-2-<(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-1-phenylbutan-1-ol(135638-23-2)

Safety Data

• Hazardous Substances Data: 135638-23-2(Hazardous Substances Data)

Upstream product

• 102680-37-5 (S)-2-((1R,2S,4R,6S,7R)-1,10,10-Trimethyl-3-oxa-tricyclo[5.2.1.0^2,6]dec-4-yloxy)-butyronitrile 
• 135638-11-8 <2R-(2a(S*),3aα,4α,7α,7aα)>-2-<(octahydro-7,8,8-trimethyl-4,7-methanobenzofuran-2-yl)oxy>-1-phenylbutan-1-on 

Downstream Products

• 40421-52-1 (1R,2S)-1-phenylpropane-1,2-diol 

Relevant articles and documents

Pheromones, III: A Simple Method to Direct the Reduction of α-Alkoxy-carbonyl Compounds

Enantiomerically pure 1,2-diols bearing optionally syn or anti configurated secondary hydroxylic groups are synthesized from acetal-protected cyanohydrins.After resolution of the diastereomers the cyanohydrins are converted into α-alkoxy-ketones by Grignard-reaction followed by reduction using common chelating or non-chelating agents.Among others syntheses of enantiomerically pure pheromones, endo-Brevicomin, exo-Brevicomin and Dispalure are given as examples.