1356668-64-8Relevant articles and documents
Synthesis of hydroxyl-containing oxindoles and 3,4-dihydroquinolin-2-ones through oxone-mediated cascade arylhydroxylation of activated alkenes
Zhang, Ming-Zhong,Liu, Long,Gou, Quan,Wang, Qi,Li, Yi,Li, Wan-Ting,Luo, Fei,Yuan, Min,Chen, Tieqiao,He, Wei-Min
, p. 8369 - 8374 (2020)
Hydroxyl-containing compounds are highly value-Added organic molecules, and the establishment of novel methodologies for their elaboration is a long-standing challenge in organic synthesis. Here the first oxone-mediated direct arylhydroxylation of activat
Palladium-catalyzed oxidative arylalkylation of activated alkenes: Dual C-H bond cleavage of an arene and acetonitrile
Wu, Tao,Mu, Xin,Liu, Guosheng
, p. 12578 - 12581 (2012/02/04)
Not one but two: The title reaction proceeds through the dual C-H bond cleavage of both aniline and acetonitrile (see scheme). The reaction affords a variety of cyano-bearing indolinones in excellent yield. Mechanistic studies demonstrate that this reaction involves a fast arylation of the olefin and a rate-determining C-H activation of the acetonitrile. Copyright
