135678-30-7

Basic information

• Product Name: 2-bromo-4-methoxyphenyl toluene-p-sulphonate
• Synonyms: 2-bromo-4-methoxyphenyl toluene-p-sulphonate
• CAS NO: 135678-30-7
• Molecular Weight: 357.225
• Mol File: 135678-30-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-bromo-4-methoxyphenyl toluene-p-sulphonate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromo-4-methoxyphenyl toluene-p-sulphonate(135678-30-7)
• EPA Substance Registry System: 2-bromo-4-methoxyphenyl toluene-p-sulphonate(135678-30-7)

Safety Data

• Hazardous Substances Data: 135678-30-7(Hazardous Substances Data)

Upstream product

• 150-76-5 4-methoxy-phenol 
• 17332-11-5 2-bromo-4-methoxyphenol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 67247-13-6 7-methoxynaphth-1-ol 

Relevant articles and documents

Synthesis of a C8 oxygenated pyranonaphthoquinone: a useful precursor to dimeric pyranonaphthoquinones

The synthesis of a pyranonaphthoquinone bearing an oxygenated substituent at C8 is reported. The oxygen substituent at C8 provides a key functionality for use as a homocoupling precursor for the synthesis of a dimeric pyranonaphthoquinone.

Pd(OAc)2-catalyzed domino reactions of 1,2-dihaloarenes and 2-haloaryl arenesulfonates with Grignard reagents: efficient synthesis of substituted fluorenes

Pd(OAc)2-catalyzed domino reactions of 1,2-dihalobenzenes and 2-haloaryl arenesulfonates with hindered Grignard reagents to form substituted fluorenes, which are believed to occur through palladium associated aryne intermediates, are described. Such palladium associated aryne reaction pathway was found to be favored by omitting the use of phosphine and N-heterocyclic carbene ligands for palladium catalysts and with better leaving groups. Our study suggested that Pd(leaving group)X associated arynes should be formed first and the sp3 C-H activation preferentially occurred at benzylic C-(1°)H bonds. The work described here provides a high yield, one-step access to substituted fluorenes from readily available 1,2-dihalobenzenes and 2-haloaryl arenesulfonates and hindered Grignard reagents, and this substituted fluorene-making method may find applications in the preparation of substituted fluorene-containing molecules including polymers.

Regioselectivity in the Reactions of Methoxydehydrobenzenes with Furans. Part 2. 2-Methoxyfuran and Methoxydehydrobenzenes

Acid-induced ring opening of adducts of furan and methoxydehydrobenzenes gives the naphthalenols derived from the more stable carbocation.The cycloadditions of methoxydehydrobenzenes containing a 3-methoxy group and 2-methoxyfuran are highly regiospecific