1356855-05-4Relevant articles and documents
Colorimetric and fluorescence turn-on sensor for biologically important anions based on carbazole derivative
Shang, Xuefang,Li, Xinjuan,Han, Jie,Jia, Shenyu,Zhang, Jinlian,Xu, Xiufang
, p. 37 - 42 (2012)
A colorimetric and fluorescent anion chemosensor containing carbazole group has been designed and synthesized based on photoinduced electron transfer (PET). The strong basic anions such as F-, AcO- and H 2PO4- resulted in significant red-shift in absorption band and enhancement in fluorescent emission intensity of the compound 1, synchronously accompanied by a "naked eye" color change from light yellow to orange-yellow in organic medium. The determination limit of sensor 1 toward H2PO4- is 1.0 × 10 - 6 mol?L- 1. 1H NMR titration experiments shed light on the nature of the interaction between 1 and the anions. Theoretical investigation further illustrated the possible binding mode of host-guest and the roles of molecular frontier orbitals in anion binding.