1357358-41-8

Basic information

• Product Name: bis[2,4,6-tris(trifluoromethyl)phenyl]borane
• Synonyms: bis[2,4,6-tris(trifluoromethyl)phenyl]borane
• CAS NO: 1357358-41-8
• Molecular Weight: 574.02
• Mol File: 1357358-41-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: bis[2,4,6-tris(trifluoromethyl)phenyl]borane(CAS DataBase Reference)
• NIST Chemistry Reference: bis[2,4,6-tris(trifluoromethyl)phenyl]borane(1357358-41-8)
• EPA Substance Registry System: bis[2,4,6-tris(trifluoromethyl)phenyl]borane(1357358-41-8)

Safety Data

• Hazardous Substances Data: 1357358-41-8(Hazardous Substances Data)

Upstream product

• 16853-85-3 lithium aluminium tetrahydride 
• 681812-02-2 bis-(2,4,6-tris-trifluoromethyl-phenyl) fluoroborane 
• 1357358-42-9 bis(2,4,6-tris(trifluoromethyl)phenyl)borane 
• 1333-74-0 hydrogen 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 

Downstream Products

• 1357358-44-1 H₂B(C₆H₂(CF₃)3)2^(1-)*HN(C₂H₅)3⁽¹⁺⁾=[H₂B(C₆H₂(CF₃)3)2][HN(C₂H₅)3] 
• 1433982-41-2 C₂₄H₉BF₁₈S 
• 1433982-40-1 C₂₆H₁₁BF₁₈ 
• 1433982-47-8 C₄₂H₂₃AuBF₁₈PS 
• 1433982-46-7 C₄₄H₂₅AuBF₁₈P 

Relevant articles and documents

Synthesis of 2-(lutidinyl)organoboranes and their reactivities against dihydrogen and pinacol borane

Two 2,4,6-tris(trifluoromethyl)phenyl-substituted 2-(lutidinyl)organoboranes (5a and 5b) were prepared. These complexes can function as intramolecular vicinal B/N frustrated Lewis pairs to heterolytically activate dihydrogen. When these complexes were treated with HBpin, two different reaction pathways took place. Whereas the reaction between 5a and HBpin affords a formal ligand-redistribution product, the reaction of 5b with HBpin leads to a dearomative dehydroborylation product.