13598-55-5

Basic information

• Product Name: THULIUM HYDRIDE
• Synonyms: THULIUM HYDRIDE;thulium trihydride;Thulium (III) hydride, REacton, 99.9% (REO);Trihydridethulium(III)
• CAS NO: 13598-55-5
• Molecular Formula: H3Tm
• Molecular Weight: 171.96
• EINECS: 237-073-5
• Mol File: 13598-55-5.mol
• Article Data: 7

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: THULIUM HYDRIDE(CAS DataBase Reference)
• NIST Chemistry Reference: THULIUM HYDRIDE(13598-55-5)
• EPA Substance Registry System: THULIUM HYDRIDE(13598-55-5)

Safety Data

• Hazardous Substances Data: 13598-55-5(Hazardous Substances Data)

Usage

InChI:InChI=1/Tm.3H/q+3;3*-1

Upstream product

• 126206-77-7 TmBr(C₄₄H₂₈N₄) 
• 7439-91-0 lanthanum 
• 7429-90-5 aluminium 
• 7440-45-1 cerium 
• 13537-18-3 thulium(III) chloride 
• 13760-79-7 thulium(III) fluoride 
• 15690-63-8 cesium chloride 
• 7647-14-5 sodium chloride 
• 12166-69-7 Tm_0.77Te 

Downstream Products

• 12039-33-7 SbTm, low pressure 
• 12039-33-7 thulium monoantimonide 
• 959973-60-5 [TmF(N,N'-bis(2,6-diisopropylphenyl)formamidine)(C₄H₈O)] 

Relevant articles and documents

COMPLEX FORMATION VS. DISPROPORTIONATION: LANTHANIDE(II) CHLORIDES, MCl//2 (M EQUVLNT Nd, Sm, Eu, Dy, Tm, Yb), UNDER THE INFLUENCE OF ALKALI CHLORIDES.

The products of the action of alkali metals (A EQUVLNT Li, Na) on lanthanide(III) chlorides, MCl//3 (M EQUVLNT Nd, Sm, Eu, Dy, Tm, Yb), principally ACl plus MCl//2 or LiCl plus LiM//2Cl//5, were reacted with CsCl in sealed tantalum containers. Complex formation (CsMcl//3) and disproportionation (to Cs//2AMCl//6 plus M) are the competing reaction types. The presence of alkali chloride (LiCl, NaCl) has no effect on complex formation of M EQUVLNT Eu, Yb, and only minimal effect for M EQUVLNT Sm. For M EQUVLNT Tm disproportionation is the principal and for M EQUVLNT Dy, Nd the exclusive process.

Effect of the 18-crown-6 and benzo-18-crown-6 on the solvent extraction and separation of lanthanide(III) ions with 8-hydroxyquinoline

The synergistic solvent extraction of 13 lanthanides with mixtures of 8-hydroxyquinoline (HQ) and the crown ethers (S) 18-crown-6 (18C6) or benzo-18-crown-6 (B18C6) in 1,2-dichloroethane has been studied. The composition of the extracted species has been

Temperature dependent rate constants for the reactions of gas phase lanthanides with N2O

The reactivity of gas phase lanthanide (Ln) atoms (Ln=La-Yb with the exception of Pm) with N2O from 298 to 623 K is reported. Lanthanide atoms were produced by the photodissociation of Ln(TMHD)3 (TMHD=2,2,6,6-tetramethyl-3,5-heptanat